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Bis(2,2′-bipyridine-κ2N,N′)chloro­copper(II) 3-carboxy­benzene­sulfonate trihydrate

✍ Scribed by Cai, Lei ;Xiao, Hong-Ping ;Zhu, Long-Guan

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
172 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

Bis(2,2 0 0 0 -bipyridine-j 2 N,N 0 0 0 )chlorocopper(II) 3-carboxybenzenesulfonate trihydrate

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The crystal structure of the title compound, [CuCl(C~12~H~8~N~2~)~2~](C~6~H~6~NO~3~S)·3H~2~O, contains Cu^II^ cations five-coordinated by one chloride anion and four N atoms of two 1,10-phenanthroline ligands. Between the the 4-aminobenzenesulfonate anions and the uncoordinated water molecules inter

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✍ Yu, Ming-Ming ;Zhang, Yu-Na ;Wei, Liu-He 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 501 KB

In the title compound, [Cu(C 10 H 8 N 2 ) 2 (H 2 O)](BF 4 ) 2 , the Cu II atom is coordinated by four N atoms and one O atom in a distorted trigonal-bipyramidal geometry. The Cu-N bond lengths are in the range 1.982 (3)-2.124 (3) A ˚, while the Cu-O distance is 2.035 (4) A ˚. The structure is stabil