[Bis(2-mercapto-1-methylimidazol-3-yl)borato](triphenylphosphine)gold(I)
✍ Scribed by Mohamed, Ahmed A. ;Rabinovich, Daniel ;Fackler, John P.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 170 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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The title compound, C 22 H 21 ClN 4 O, is used as an intermediate for the synthesis of biologically active compounds. Geometric parameters are in the usual ranges. The packing is stabilized by O-HÁ Á ÁN hydrogen bonding.
In the title complex, {[Ag(C~16~H~18~N~4~)]NO~3~}~__n__~, the cationic part forms infinite chains where the Ag^I^ ions are coordinated in a slightly bent fashion by two N-donor atoms of imidazole rings of two distinct ligand molecules. The nitrate anions interact weakly with the silver cations to fo
The title compound, {[Ag(C~14~H~14~N~2~)](C~8~H~10~NO~3~S)}~__n__~, adopts a polymeric chain structure, where each Ag^I^ cation binds two N atoms from two different 1,2-bis[(1__H__-imidazol-1-yl)methyl]benzene (IBI) ligands in a linear coordination geometry. Each IBI ligand bridges two neighbouring