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catena-Poly[[silver(I)-μ-1,2-bis[(1H-imidazol-1-yl)methyl]benzene-κ2N3:N3′] 2-amino-3,5-dimethylbenzenesulfonate]

✍ Scribed by Liu, Hai-Yan ;Ma, Ji-Cheng ;Yang, Jin

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 476 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s160053680704963x

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✦ Synopsis

The title compound, {Ag(C~14~H~14~N~2~)}~n~, adopts a polymeric chain structure, where each Ag^I^ cation binds two N atoms from two different 1,2-bis[(1__H__-imidazol-1-yl)methyl]benzene (IBI) ligands in a linear coordination geometry. Each IBI ligand bridges two neighbouring Ag^I^ atoms to form the polymer chain. The 2-amino-3,5-dimethylbenzenesulfonate counter-ion does not coordinate to the Ag^I^ centre but forms an intramolecular N—H...O hydrogen bond.

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