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Bis(2-hydroxybenzonitrile-κN)dimethylbis(trimethylphosphine-κP)cobalt(III) iodide

✍ Scribed by Yu, Fengli ;Zhou, Jin ;Li, Xiaoyan

Book ID
104492076
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
345 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Co(CH~3~)~2~(C~7~H~5~NO)~2~(C~3~H~9~P)~2~]I, the Co^III^ atom lies in the centre of a distorted octahedron. The central Co^III^ atom is coordinated by the N atoms of two 2-hydroxybenzonitrile ligands, which are positioned in the equatorial plane. The cation lies on a mirror plane (passing through Co and the phosphine ligands) and has approximate C__2__v symmetry except for the OH groups. The anion also lies on a mirror plane.

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