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trans-Aqua­bis(glyoximato-κ2N,N′)nitro­cobalt(III)

✍ Scribed by Rubin-Preminger, Janice M. ;Englert, Ulli


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
236 KB
Volume
62
Category
Article
ISSN
1600-5368

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Aqua­bis(dimethyl­yglyoximato-κ2N,N′)nit
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The title compound, [Co(C 4 H 7 N 2 O 2 ) 2 (NO 2 )(H 2 O)]ÁH 2 O, is a distorted octahedral Co III complex with two dimethylglyoximate ligands in the equatorial plane and nitro and aqua substituents in the axial positions. The two dimethylglyoximate ligands are involved in intramolecular hydrogen b

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Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.025 wR factor = 0.066 Data-to-parameter ratio = 11.6 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.