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Aqua­bis(dimethyl­yglyoximato-κ2N,N′)nitro­cobalt(III) monohydrate

✍ Scribed by Rubin-Preminger, Janice M. ;Englert, Ulli

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
108 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Co(C 4 H 7 N 2 O 2 ) 2 (NO 2 )(H 2 O)]ÁH 2 O, is a distorted octahedral Co III complex with two dimethylglyoximate ligands in the equatorial plane and nitro and aqua substituents in the axial positions. The two dimethylglyoximate ligands are involved in intramolecular hydrogen bonds. Coordinated and uncoordinated water molecules participate in O-HÁ Á ÁO hydrogen bonds, linking the cobalt complexes into a three-dimensional network.

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