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Aqua­bis(1,2-ethanediamine-κ2N,N′)hydroxidocobalt(III) naphthalene-1,5-disulfonate monohydrate

✍ Scribed by Ou, Guang-Chuan ;Zhang, Min ;Yuan, Xian-You ;Ng, Seik Weng


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
188 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The Co^III^ atom in the title compound, Co(C~2~H~8~N~2~)~2~(OH)(H~2~O)·H~2~O, exhibits an octahedral coordination geometry, with the hydroxide and water ligands occupying cis sites. Adjacent cations are linked into linear chains through hydrogen-bonded OH...OH~2~ units. The Co^III^ atom lies on a twofold rotation axis and the naphthalene-1,5-disulfonate dianion lies on a centre of inversion.


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