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[N,N-Bis(carboxy­meth­yl)-l-leucinato](1,2-ethanediamine)cobalt(III) monohydrate

✍ Scribed by Kato, Takashi ;Fujii, Tatsuya ;Ozawa, Tomohiro ;Funahashi, Yasuhiro ;Masuda, Hideki

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
225 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The Co atom in the title compound, [Co(C 10 H 14 NO 6 )-(C 2 H 8 N 2 )]ÁH 2 O, has an octahedral geometry with tetradentate N,N-bis(carboxymethyl)-l-leucine (l-bcmle) and bidentate ethylenediamine (en) ligands. The complexes and water molecules are linked via N-HÁ Á ÁO and O-HÁ Á ÁO hydrogen bonds, forming layers perpendicular to the c axis. Between these hydrophilic layers, hydrophobic bilayers are formed by the isobutyl groups of the l-bcmle ligands.

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