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Bis(2,2′-bipyridine-κ2N,N′)(carbonato-κ2O,O′)cobalt(III) trifluoromethanesulfonate

✍ Scribed by Lv, Yang-Xiao ;Ling, Yun ;Li, Huan ;Zhang, Lei

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
465 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Co(CO 3 )(C 10 H 8 N 2 ) 2 ](CF 3 SO 3 ), the Co III ion is coordinated by four N atoms from two chelating 2,2 0 -bipyridine ligands and two O atoms from a bidentate chelating carbonate anion, and has a distorted octahedral environment. C-HÁ Á ÁO hydrogen bonding is observed between bipyridine ligands and uncoordinated (CF 3 SO 3 ) À anions and between bipyridine and carbonate ligands.

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