In the title compound, [Co(CO 3 )(C 10 H 8 N 2 ) 2 ](CF 3 SO 3 ), the Co III ion is coordinated by four N atoms from two chelating 2,2 0 -bipyridine ligands and two O atoms from a bidentate chelating carbonate anion, and has a distorted octahedral environment. C-HÁ Á ÁO hydrogen bonding is observed
Tetra-n-butylamine(carbonato-κ2O,O′)cobalt(III) n-butylcarbamate dihydrate
✍ Scribed by Keene, Tony D. ;Hursthouse, Michael B. ;Price, Daniel J.
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 277 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
T. D. Keene et al. [Co(CO 3 )(C 4 H 11 N) 4 ](C 5 H 10 NO 2 )Á2H 2 O m381
📜 SIMILAR VOLUMES
The title compound, [Co(C~2~H~4~NO~2~)~3~], is a mononuclear cobalt(III) complex. The Co^III^ atom is six-coordinated by three N atoms and three O atoms from three chelating glycinate ligands, forming a slightly distorted octahedral configuration. In the crystal structure, the molecules are linked t
Single-crystal X-ray study T = 571 K Mean '(C±C) = 0.012 A Ê R factor = 0.047 wR factor = 0.123 Data-to-parameter ratio = 13.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, {[Co(C~8~H~4~O~5~)(C~10~H~8~N~2~)]·2H~2~O]}~__n__~ or {[Co(OH-BDC)(2,2′-bipy)]·2H~2~O]}~__n__~ (where OH-H~2~BDC is 5-hydroxyisophthalic acid and 2,2′-bipy is 2,2′-bipyridine), the Co atoms are chelated by two N atoms from the 2,2′-bipy ligand and by four O atoms from OH-BDC l
Bis(2,2 0 0 0 -bipyridine-j 2 N,N 0 0 0 )(nitrato-j 2 O,O 0 0 0 )cobalt(II) iodide tetrahydrate Radoslava Ivanikova ´,a Ingrid Svoboda, b Anna Mas ˇlejova ´,a Blaz ˇena Papa ´nkova ´a and Hartmut Fuess b \*