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Bis[(1,4,7,10,13,16-hexa­oxacyclo­octa­decane)­potassium] carbonyl­tricyano­rhodate(I) acetonitrile solvate

✍ Scribed by Whaley, Curtis M. ;Rauchfuss, Thomas B. ;Wilson, Scott R.

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
132 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, [K(C 12 H 24 )] 2 [Rh(CN) 3 (CO)]ÁC 2 H 3 N, the Rh atom is coordinated by three cyanide ligands and one carbonyl ligand in a square-planar geometry. The K atom in each cation is coordinated by six O atoms from the crown ether and one N atom from a cyanide ligand.

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In the title complex, [Cu 2 I 2 (C 12 H 8 N 2 ) 2 ]ÁC 2 H 3 N, two Cu I atoms are bridged by two I atoms and each Cu I atom is chelated by a 1,10-phenanthroline ligand to give four-coordinate tetrahedral geometry.

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