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(1,4,7,10,13,16-Hexaoxa­cyclo­octa­decane)­potassium dithiocyanatoaurate(I)

✍ Scribed by Coker, Nathan L. ;Krause Bauer, Jeanette A. ;Elder, R. C.

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
673 KB
Volume
60
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES

1,4,7,10,13,16-Hexaoxacyclo­octa­decane–
1,4,7,10,13,16-Hexaoxacyclo­octa­decane–ammonia (1/2)
✍ Nuss, Hanne ;Jansen, Martin 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 169 KB

The title compound, a 1:2 adduct of 18-crown-6 and ammonia, C 12 H 24 O 6 Á2NH 3 , has inversion symmetry. Two ammonia molecules are connected to the crown ether above and below the cyclic plane via N-HÁ Á ÁO hydrogen bonds to form a disclike adduct.

Bis[(1,4,7,10,13,16-hexa­oxacyclo­octa­d
Bis[(1,4,7,10,13,16-hexa­oxacyclo­octa­decane)­potassium] carbonyl­tricyano­rhodate(I) acetonitrile solvate
✍ Whaley, Curtis M. ;Rauchfuss, Thomas B. ;Wilson, Scott R. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 132 KB

In the title complex, [K(C 12 H 24 )] 2 [Rh(CN) 3 (CO)]ÁC 2 H 3 N, the Rh atom is coordinated by three cyanide ligands and one carbonyl ligand in a square-planar geometry. The K atom in each cation is coordinated by six O atoms from the crown ether and one N atom from a cyanide ligand.