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Bis[(1,4,7,10,13,16-hexa­oxocyclo­octa­decane)­caesium(I)] di-μ2-diselenido-bis­[selenidoarsenate(III)]

✍ Scribed by Van Almsick, Tobias ;Sheldrick, William S.


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
629 KB
Volume
61
Category
Article
ISSN
1600-5368

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Bis[(1,4,7,10,13,16-hexa­oxacyclo­octa­d
✍ Whaley, Curtis M. ;Rauchfuss, Thomas B. ;Wilson, Scott R. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 132 KB

In the title complex, [K(C 12 H 24 )] 2 [Rh(CN) 3 (CO)]ÁC 2 H 3 N, the Rh atom is coordinated by three cyanide ligands and one carbonyl ligand in a square-planar geometry. The K atom in each cation is coordinated by six O atoms from the crown ether and one N atom from a cyanide ligand.