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Biosynthesis of Phosphonic and Phosphinic Acid Natural Products

โœ Scribed by Metcalf, William W. (author);Van Der Donk, Wilfred A. (author)

Book ID
120331267
Publisher
Annual Reviews
Year
2009
Tongue
English
Weight
754 KB
Volume
78
Category
Article
ISSN
0066-4154

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## Abstract Dialkyl phosphonates add in a 1,2 fashion to the C = N bond in 5,5โ€dimethylโ€3โ€thiozolines **2** to form dialkyl __rac__โ€(4โ€thiazolidinyl)phosphonates **3a** โ€“ **e**. Upon hydrolysis of **3a** __rac__โ€(1โ€aminoโ€2โ€mercaptoโ€2โ€methylpropyl)phosphonic acid (**4a**), the phosphonic acid analog