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Synthesis and Properties of Phosphinic and Phosphonic Acid Anhydrides *

โœ Scribed by Moedritzer, Kurt


Book ID
121469047
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
480 KB
Volume
83
Category
Article
ISSN
0002-7863

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Phosphonic and Phosphinic Acid Analogs o
โœ Drauz, Karlheinz ;Koban, Hans Gรผnter ;Martens, Jรผrgen ;Schwarze, Wolfgang ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 285 KB

## Abstract Dialkyl phosphonates add in a 1,2 fashion to the C = N bond in 5,5โ€dimethylโ€3โ€thiozolines **2** to form dialkyl __rac__โ€(4โ€thiazolidinyl)phosphonates **3a** โ€“ **e**. Upon hydrolysis of **3a** __rac__โ€(1โ€aminoโ€2โ€mercaptoโ€2โ€methylpropyl)phosphonic acid (**4a**), the phosphonic acid analog