Benzyltrimethylammonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(III)
✍ Scribed by Xu, Wen ;Yu, Wentao ;Xue, Gang ;Fang, Qi
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 145 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.007 A Ê R factor = 0.038 wR factor = 0.095 Data-to-parameter ratio = 19.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.009 A Ê R factor = 0.064 wR factor = 0.185 Data-to-parameter ratio = 19.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, (C~7~H~12~NS)[Ni(C~3~S~5~)~2~], the dihedral angle between the thiazole ring of the cation and the plane of the anion is 8.0 (2)°. In the crystal structure, S...S intermolecular interactions between the anions form a distorted honeycomb structure parallel to the (002) plane, wi