𝔖 Bobbio Scriptorium
✦   LIBER   ✦

2,3-Diethylthiazolium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(III)

✍ Scribed by Tomiyama, Etsuko ;Tomono, Kazuaki ;Miyamura, Kazuo

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
907 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

In the title complex, (C~7~H~12~NS)[Ni(C~3~S~5~)~2~], the dihedral angle between the thiazole ring of the cation and the plane of the anion is 8.0 (2)°. In the crystal structure, S...S intermolecular interactions between the anions form a distorted honeycomb structure parallel to the (002) plane, with cavities ∼12.34 Å in diameter. The cavities are filled with cations. The cations and anions are linked via S...S [3.6657 (15) and 3.6240 (15) Å] and C—H...S interactions.

📜 SIMILAR VOLUMES

N-(4-Fluoro­benz­yl)pyridinium bis­(2-th
N-(4-Fluoro­benz­yl)pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(III)
✍ Lou, Weijiang ;Yang, Guozhong ;Su, Yang ;Tao, Ruojie 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 99 KB

In the title ion-pair compound, (C 12 H 11 FN)[Ni(C 3 S 5 ) 2 ], the Ni III atom is coordinated by four sulfur atoms of the two 2thioxo-1,3-dithiole-4,5-dithiolate ligands in a square-planar geometry. Weak C-HÁ Á ÁS interactions are found, resulting in a three-dimensional supramolecular network.