1-Methyl-N-(4-nitrobenzyl)pyridinium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(III)
✍ Scribed by Tong, Wen-Jun ;Liu, Ling ;Meng, Qing-Jin ;Li, Yi-Zhi ;Yao, Yuan-Gen
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 385 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.009 A Ê R factor = 0.064 wR factor = 0.185 Data-to-parameter ratio = 19.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title ion-pair compound, (C 12 H 11 FN)[Ni(C 3 S 5 ) 2 ], the Ni III atom is coordinated by four sulfur atoms of the two 2thioxo-1,3-dithiole-4,5-dithiolate ligands in a square-planar geometry. Weak C-HÁ Á ÁS interactions are found, resulting in a three-dimensional supramolecular network.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.007 A Ê R factor = 0.038 wR factor = 0.095 Data-to-parameter ratio = 19.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.