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Benzimidazolin-2-ylidene–palladium-catalysed coupling reactions of aryl halides

✍ Scribed by Yetkin Gök; Nevin Gürbüz; İsmail Özdemir; Bekir Çetinkaya; Engin Çetinkaya

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
116 KB
Volume
19
Category
Article
ISSN
0268-2605

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✦ Synopsis

The in situ prepared three-component system Pd(OAc) 2 -1,3-dialkylbenzimidazolium chlorides (2a-f) and Cs 2 CO 3 catalyses, quantitatively, the Suzuki cross-coupling of deactivated aryl chlorides and Heck coupling reactions of aryl bromide and iodide substrates. The 1,3-dialkylbenzimidazolium salts (2a-f) were characterized by conventional spectroscopic methods and elemental analysis.

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