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Behaviour of silver(II) in phosphoric acid media and a general mechanism for solvent oxidation

✍ Scribed by G.A. Rechnitz; S.B. Zamochnick


Book ID
118989860
Publisher
Elsevier Science
Year
1965
Tongue
English
Weight
433 KB
Volume
12
Category
Article
ISSN
0039-9140

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Mechanism of oxidation of iron(II) chela
✍ Parupalli J. Lakshmi; Kamatala C. Rajanna; Pondichery K. Saiprakash πŸ“‚ Article πŸ“… 1996 πŸ› Springer 🌐 English βš– 534 KB

Oxidation of the Fe n chelates [FeL l (L = phen or bipy) by Cr w and Mn TM in H2SO 4 medium was found to proceed through the formation of a bimetallic insertion complex which decomposes in the slow step, followed by electron transfer from [FeLl to the oxidant. The reactions are catalysed by both ani