Kinetics and mechanism of the oxidation of formic acid by silver(II) in nitric acid media
β Scribed by Miller, Leo.; Morrow, Jack I.
- Book ID
- 124058434
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 370 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0020-1669
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The reaction between formic acid and bromine in strongly acid aqueous media at 298 K Brz + HCOOH -2 Br-+ 2 H+ + COz was studied by absorption spectrophotometry (A = 447 nm). Reaction rates, expressed as H = -d[Brz]/dt, depend on the concentrations of HCOOH (0.3-2.4M), Br2[(2.7-13.6) X 10-3M], H+ (0.
Spectrophotometric methods were used to investigate the rate of the reaction of Br:! with HCOOH in aqueous, acidic media. The reaction products are Br-and COa. The kinetics of this reaction are complicated by both the formation of Br3-as Bris formed and the dissociation of HCOOH into HCOO-and H+. Pr
The kinetics of the reaction between nitric acid and formaldehyde have been studied by spectrophotometry. The reaction is autocatalytic. A two-step mechanism is proposed, which accounts for this behavior and describes the effect of reactant concentrations on the characteristics of the kinetic curves