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Kinetics and mechanism of autocatalytic oxidation of formaldehyde by nitric acid

✍ Scribed by Monika Horváth; István Lengyel; György Bazsa

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
449 KB
Volume
20
Category
Article
ISSN
0538-8066

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✦ Synopsis

The kinetics of the reaction between nitric acid and formaldehyde have been studied by spectrophotometry. The reaction is autocatalytic. A two-step mechanism is proposed, which accounts for this behavior and describes the effect of reactant concentrations on the characteristics of the kinetic curves: the length of the induction period, t,, the maximum rate, rmax of nitrous acid production and the final product concentration, cp

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