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Azabiocyclo[3.2.0]heptane-3,4-dione (10): A Thermal Azonia 1,3-Shift of 2-Azabicyclo[3.2.0]hept-2-enes to 2-Azanorborn-2-enes

✍ Scribed by Sano, Takehiro; Tanaka, Kazuhiko; Horiguchi, Yoshie; Tsuda, Yoshisuke

Book ID
126918660
Publisher
Japan Institute of Heterocyclic Chemistry
Year
1985
Tongue
English
Weight
130 KB
Volume
23
Category
Article
ISSN
0385-5414

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## Abstract The chemistry of the highly substituted cyclobutanone derivative 2, which is easily accessible from 1, is dominated by the steric hindrance caused by the substitutents: Reduction with hydride reagents and nucleophilic additions with methyllithium are less stereoselective than correspond