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1-Azabicyclo[3,2,0]hept-3-ene-2,7-diones. A new heterocyclic system

โœ Scribed by Hatanaka, N.; Ohta, H.; Simamura, O.; Yoshida, M.


Book ID
121508418
Publisher
Royal Society of Chemistry
Year
1971
Weight
161 KB
Volume
21
Category
Article
ISSN
0577-6171

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Allylic oxidation of 4-allyl-1-dimethyl-t-butylsilylazetidin-2ones (5,7) gave the 4-(l-hydroxyprop-2-ene-1-yl) derivatives (6,8). Radical benzoyloxylation of the silylated 8-oxo-7-azabicyclo[4.2.O]oct-3ene (18) provided four allylic monobenzoates. Progression of ( ) and ( ) afforded, respectively,