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Substituted 1-phosphabicyclo [3.2.0] hept-4-enes

✍ Scribed by Ju.G. Trishin; I.V. Konovalova; R.N. Burangulova; L.A. Burnaeva; V.N. Chistokletov; A.N. Pudovik


Book ID
108382693
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
228 KB
Volume
30
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Tricyclo[4.1.0.01,3] hept-4-enes as Inte
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3. On the other hand, the rearrangement of the tricycle 1 could take place via retro-Diels-Alder reaction or via diradicals as intermediates. The conversion into 3 might be initiated by rupture of the C2-C3 and/or C1-C6 bonds. Hydrogenation (Pt/C, pentane) of 1 affords 4-and 5methyl-2,3-benzobicycl

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## Abstract The chemistry of the highly substituted cyclobutanone derivative 2, which is easily accessible from 1, is dominated by the steric hindrance caused by the substitutents: Reduction with hydride reagents and nucleophilic additions with methyllithium are less stereoselective than correspond

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