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Atomic layer deposited WNxCy films growth on SiC surfaces

โœ Scribed by A. Martin Hoyas; C.M. Whelan; J. Schuhmacher; K. Maex; J.P. Celis


Book ID
104051556
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
138 KB
Volume
83
Category
Article
ISSN
0167-9317

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โœฆ Synopsis


The growth of tungsten nitride carbide, WN x C y , films obtained by atomic layer deposition (ALD), using tri-ethylboron, tungsten hexafluoride and ammonia precursors is determined by the density and type of substrate reactive sites. During an initial period, referred to as transient regime, the SiC oxidation state and the tri-ethylboron pulse time determine the amount of metal deposited. WN x C y growth on SiC is similar to that on PECVD SiO 2 explained by decomposition of the tri-ethylboron precursor, giving rise to a carbon rich WN x C y -oxide interface.


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