Asymmetric Transfer Hydrogenation of Aromatic Ketones by Rh(I)/Bimorpholine Complexes.
β Scribed by Kadri Kriis; Tonis Kanger; Margus Lopp
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 109 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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## Abstract The osmium compound __trans__,__cis__β[OsCl~2~(PPh~3~)~2~(Pyme)] (1) (Pyme=1β(pyridinβ2βyl)methanamine), obtained from [OsCl~2~(PPh~3~)~3~] and Pyme, thermally isomerizes to __cis__,__cis__β[OsCl~2~(PPh~3~)~2~(Pyme)] (2) in mesitylene at 150βΒ°C. Reaction of [OsCl~2~(PPh~3~)~3~] with Ph~
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