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ChemInform Abstract: Asymmetric Transfer Hydrogenation of Olefins and Ketones Catalyzed by Metal Complexes

✍ Scribed by S. HASHIGUCHI; A. FUJII; R. NOYORI


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.


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Osmium Pyme Complexes for Fast Hydrogena
✍ Walter Baratta; Maurizio Ballico; Alessandro Delβ€…Zotto; Katia Siega; Santo Magno πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 259 KB

## Abstract The osmium compound __trans__,__cis__‐[OsCl~2~(PPh~3~)~2~(Pyme)] (1) (Pyme=1‐(pyridin‐2‐yl)methanamine), obtained from [OsCl~2~(PPh~3~)~3~] and Pyme, thermally isomerizes to __cis__,__cis__‐[OsCl~2~(PPh~3~)~2~(Pyme)] (2) in mesitylene at 150 °C. Reaction of [OsCl~2~(PPh~3~)~3~] with Ph~