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Asymmetric Total Synthesis of Nigerone

✍ Scribed by DiVirgilio, Evan S.; Dugan, Elizabeth C.; Mulrooney, Carol A.; Kozlowski, Marisa C.

Book ID: 127005619
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 106 KB
Volume: 9
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol062468y

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## Abstract An enantioselective synthesis of the chiral bisnaphthopyrone natural product nigerone and its enantiomer, __ent__‐nigerone, has been realized. The use of constrained 2‐naphthol substrates was critical to producing highly functionalized chiral 1,1′‐binaphthols __via__ asymmetric oxidativ

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