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Asymmetric synthesis of difluorocyclopropanes

โœ Scribed by Takeo Taguchi; Akira Shibuya; Hirofumi Sasaki; Jun-ichi Endo; Tsutomu Morikawa; Motoo Shiro

Book ID
108036215
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
245 KB
Volume
5
Category
Article
ISSN
0957-4166

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ChemInform Abstract: Synthesis of (+)-(R)-1-Amino-2,2-difluorocyclopropane-1-carboxylic Acid Through Lipase-Catalyzed Asymmetric Acetylation.
โœ Masayuki Kirihara; Tomofumi Takuwa; Masashi Kawasaki; Hiroko Kakuda; Shun-ichi H ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 2 views

Synthesis of (+)-(R)-1-Amino-2,2-difluorocyclopropane-1-carboxylic Acid Through Lipase-Catalyzed Asymmetric Acetylation. -Hydrochloride (VIII) of the title compound is prepared via the asymmetric acetylation of diol (III) as the key step. Several enzymes and conditions are investigated to obtain th