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Asymmetric Hydroformylation of Styrene Catalyzed by Pyranoside Diphosphite-Rh(I) Complexes

✍ Scribed by Xiaojing JIA; Lailai WANG; Albert S.C. CHAN; Yueming LI


Book ID
104452736
Publisher
Elsevier Science
Year
2007
Weight
303 KB
Volume
28
Category
Article
ISSN
1872-2067

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Asymmetric hydroformylation of conjugate
✍ Toshihide Horiuchi; Tetsuo Ohta; Eiji Shirakawa; Kyoko Nozaki; Hidemasa Takaya πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 503 KB

Asymmetric hydroformylation of conjugated dienes has been investigated using (R,S)-BINAPHOS-Rh(I) complex as a catalyst [(R,S)-BINAPHOS = (R)-2-(diphenylphosphino)-l,l'binaphthalen-2'-yl (S)-I,1 '-binaphthalene-2,2'-diyl phosphite]. Optically active 13,~,-unsaturated aldehydes were obtained in high