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Asymmetric hydroformylation of styrene catalyzed by carbohydrate diphosphite-Rh(I) complexes

✍ Scribed by Diéguez, Montserrat; Pàmies, Oscar; Ruiz, Aurora; Claver, Carmen


Book ID
111980230
Publisher
Royal Society of Chemistry
Year
2002
Tongue
English
Weight
184 KB
Volume
26
Category
Article
ISSN
1144-0546

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Asymmetric hydroformylation of conjugate
✍ Toshihide Horiuchi; Tetsuo Ohta; Eiji Shirakawa; Kyoko Nozaki; Hidemasa Takaya 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 503 KB

Asymmetric hydroformylation of conjugated dienes has been investigated using (R,S)-BINAPHOS-Rh(I) complex as a catalyst [(R,S)-BINAPHOS = (R)-2-(diphenylphosphino)-l,l'binaphthalen-2'-yl (S)-I,1 '-binaphthalene-2,2'-diyl phosphite]. Optically active 13,~,-unsaturated aldehydes were obtained in high