𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Asymmetric Hydroformylation of Heterocyclic Olefins Catalyzed by Chiral Phosphine−Phosphite−Rh(I) Complexes

✍ Scribed by Horiuchi, Toshihide; Ohta, Tetsuo; Shirakawa, Eiji; Nozaki, Kyoko; Takaya, Hidemasa

Book ID
126002451
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
264 KB
Volume
62
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Asymmetric hydroformylation of conjugate
Asymmetric hydroformylation of conjugated dienes catalyzed by chiral phosphine-phosphite-Rh(I) complex
✍ Toshihide Horiuchi; Tetsuo Ohta; Eiji Shirakawa; Kyoko Nozaki; Hidemasa Takaya 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 503 KB

Asymmetric hydroformylation of conjugated dienes has been investigated using (R,S)-BINAPHOS-Rh(I) complex as a catalyst [(R,S)-BINAPHOS = (R)-2-(diphenylphosphino)-l,l'binaphthalen-2'-yl (S)-I,1 '-binaphthalene-2,2'-diyl phosphite]. Optically active 13,~,-unsaturated aldehydes were obtained in high

ChemInform Abstract: Asymmetric Hydrofor
ChemInform Abstract: Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by Chiral Phosphine-Phosphite-Rh(I) Complex.
✍ T. HORIUCHI; T. OHTA; E. SHIRAKAWA; K. NOZAKI; H. TAKAYA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 1 views

Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by Chiral Phosphine-Phosphite-Rh(I) Complex. -Optically active β,γ-unsaturated aldehydes are obtained in high regio-and enantioselectivities from dienes like (II) and (VI) by the title reaction with chiral (R,S)-BINAPHOS-Rh(I) complex as ca

ChemInform Abstract: Mechanistic Aspects
ChemInform Abstract: Mechanistic Aspects of Asymmetric Hydroformylation of Olefins Catalyzed by Chiral Phosphine-Phosphite-Rhodium(I) Complexes.
✍ T. HORIUCHI; E. SHIRAKAWA; K. NOZAKI; H. TAKAYA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 2 views

## Mechanistic Aspects of Asymmetric Hydroformylation of Olefins Catalyzed by Chiral Phosphine-Phosphite-Rhodium(I) Complexes. -The effects of the partial pressure of CO (II) and H2 on the reaction rate and selectivity of the asymmetric hydroformylation of 1-hexene ( Ia) and styrene (Ib) are exam