Hydroformylation of olefins catalyzed by chiral phosphite-Rh(I) complexes
โ Scribed by Ming Yan; Xingshu Li; Albert Sunchi Chan
- Book ID
- 105727055
- Publisher
- Springer
- Year
- 2003
- Tongue
- English
- Weight
- 121 KB
- Volume
- 48
- Category
- Article
- ISSN
- 1001-6538
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Asymmetric hydroformylation of conjugated dienes has been investigated using (R,S)-BINAPHOS-Rh(I) complex as a catalyst [(R,S)-BINAPHOS = (R)-2-(diphenylphosphino)-l,l'binaphthalen-2'-yl (S)-I,1 '-binaphthalene-2,2'-diyl phosphite]. Optically active 13,~,-unsaturated aldehydes were obtained in high
Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by Chiral Phosphine-Phosphite-Rh(I) Complex. -Optically active ฮฒ,ฮณ-unsaturated aldehydes are obtained in high regio-and enantioselectivities from dienes like (II) and (VI) by the title reaction with chiral (R,S)-BINAPHOS-Rh(I) complex as ca