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Asymmetric ene reaction catalyzed by chiral organoaluminum reagent

โœ Scribed by Keiji Maruoka; Yorihisa Hoshino; Tadashi Shirasaka; Hisashi Yamamoto

Book ID
108381663
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
235 KB
Volume
29
Category
Article
ISSN
0040-4039

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Reaction of Cis Hydroxy Epoxide 63 with Dimsylpotassium. Preparat ion of ( 1 S *, 1 'S * ,3'R * ,8'S *) -1 -(2',7'-Dioxabic y clo[ 4.4.01decan-3'yl)-2-propanol (65) and Its Acetate ( ). The bicyclic compound 65 was prepared from compound 63 (19.8 mg, 0.1 mmol) by the same procedure used to convert 6