Asymmetric Claisen rearrangement catalyzed by chiral organoaluminum reagent
β Scribed by Maruoka, Keiji; Banno, Hiroshi; Yamamoto, Hisashi
- Book ID
- 127169428
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 797 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Cbiral induction (?2-74% diastervomeric excess) in an auxiliary-reagent mediated aza-Claisen rearrangement yielding 2-and 3-m&hyZpent-&en&c acids has been demonstrated. Claisen rearrangements ([3,3] sigmatropic reorganization of ally1 vinyl hetero-systems) have been employed in numerous aspects of o
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