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Asymmetric Diels-Alder reaction catalyzed by a chiral titanium reagent

✍ Scribed by Narasaka, Koichi; Iwasawa, Nobuharu; Inoue, Masayuki; Yamada, Tohru; Nakashima, Masako; Sugimori, Jun

Book ID
120082917
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
813 KB
Volume
111
Category
Article
ISSN
0002-7863

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Asymmetric Diels-Alder reaction catalyze
Asymmetric Diels-Alder reaction catalyzed by a chiral titanium reagent
✍ Narasaka, Koichi; Iwasawa, Nobuharu; Inoue, Masayuki; Yamada, Tohru; Nakashima, πŸ“‚ Article πŸ“… 1989 πŸ› American Chemical Society 🌐 English βš– 813 KB

Reaction of Cis Hydroxy Epoxide 63 with Dimsylpotassium. Preparat ion of ( 1 S *, 1 'S * ,3'R * ,8'S *) -1 -(2',7'-Dioxabic y clo[ 4.4.01decan-3'yl)-2-propanol (65) and Its Acetate ( ). The bicyclic compound 65 was prepared from compound 63 (19.8 mg, 0.1 mmol) by the same procedure used to convert 6