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Efficient Asymmetric Catalysis of Chiral Organoaluminum Complex for Enantioselective Ene Reactions of Aldehydes.

✍ Scribed by Takashi Ooi; Kohsuke Ohmatsu; Daisuke Uraguchi; Keiji Maruoka

Publisher
John Wiley and Sons
Year
2004
Weight
129 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract The synthesis of new chiral amino alcohols by Heck arylation of an enecarbamate is described. These compounds were used as chiral ligands for the catalytic asymmetric arylation of aldehydes and can be easily recovered. Chiral, nonracemic diarylmethanols were obtained in high yields and