The chiral vinyl sulfsximines lb and q have been prepared. The effect of cations -(Li+, Zn'+) on the stereochemical outcome of their conjugate addition reactions with organocopper reagents is reported. Recently we reported that chiral vinyl sulfoximines la underwent conjugate addition reactions wit
Asymmetric conjugate addition of organometallic reagents to chiral vinyl sulfoximines
β Scribed by Pyne, Stephen G.
- Book ID
- 126034913
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 893 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Asymmetric Addition of Organometallic Reagents to Chiral Ξ±-Alkoxy Hydrazones. -The diastereoselective addition of three different types of nucleophilic reagents to three different Ξ±-alkoxy hydrazones is studied. With exception of the reation of the silylated hydrazone (Ib) with the heterogeneous 1:
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