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Application of the Meyer-Neldel rule to the electrical conductivity of Nasicon

✍ Scribed by W. Bogusz; D.E. Kony; F. Krok


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
329 KB
Volume
15
Category
Article
ISSN
0921-5107

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✦ Synopsis


It was checked that the Meyer-Neldel rule is applicable to ionic conductivity of pure Nasicon as well as of Nasicon doped with CaO, CoO and MgO. The results seem to suggest that the knee on Arrhenius plots obtained for investigated samples corresponds to an order-disorder transition that occurs in Nasicon materials.


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The application of NASICON (Na2Zr2Si2PO1
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The solid-state galvanic cell with NASICON as au auxiliary electrolyte was built. The standard Free enthalpy, entropy and enthalpy of beta-alumina Formation as well as the Na,O-activity in the alphaalumina-beta-alumina coexistence region were determined in the temperature range 97G1220K. The limitin