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The application of NASICON (Na2Zr2Si2PO12) to the thermodynamic study of beta-alumina

✍ Scribed by G. Róg; S. Koziński; A. Kozlowska-Róg

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
237 KB
Volume
28
Category
Article
ISSN
0013-4686

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✦ Synopsis

The solid-state galvanic cell with NASICON as au auxiliary electrolyte was built. The standard Free enthalpy, entropy and enthalpy of beta-alumina Formation as well as the Na,O-activity in the alphaalumina-beta-alumina coexistence region were determined in the temperature range 97G1220K. The limiting temperature of spontaneous decomposition of beta-alumina was also estimated. The results were compared with those obtained by other authors.

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