Up to four fixed resonances are observed in the title system independent of the composition: NaZr2(P04)X (J&OS), Na3Zr1.S(P04)3 (y>O), Na4P20r (y>O) and a fourth line which we are so far unable to interpret in structural terms. The "P chemical shift parameters of NasZr,.S(P04)s are: 6= -11.9 k 0.3 p
✦ LIBER ✦
29Si and 31P MAS NMR study of the NASICON system Na1+χZr2(SiO4)χ(PO4)3-χ
✍ Scribed by C. Jäger; G. Scheler; U. Sternberg; S. Barth; A. Feltz
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 324 KB
- Volume
- 147
- Category
- Article
- ISSN
- 0009-2614
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📜 SIMILAR VOLUMES
31P MAS NMR study of the NASICON system
✍
C. Jäger; S. Barth; A. Feltz
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1988
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Elsevier Science
🌐
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⚖ 242 KB
23Na NMR study of the nasicon system Na1
✍
C. Jäger; S. Barth; A. Feltz
📂
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1989
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⚖ 264 KB
The solid solution Na,+ar,(P0,),\_,( ),has been investigated by \*)Na NMR. The parameters of the quadrupole tensor of the Na( 1) positions in NaZr2(P04), are yq= 1.2kO.l MHz and ~=0.04+0.04. Those for the Na( 1) and Na(2) sites in Na,Zr,(SiO,), are found to be Na( 1): vq= 1.04+0.1 MHz, ~=0.84?0.7; N