By E. CALITZENSTEIN (the laic) and C. \\'OOLF The chlorination of ethylene in the liquid phase to form I : 2dichloroethane (ethylene dichloride), has been investigated in some detail, catalysts such as antimony trichloride and ferric chloride being employed, at tempentures hctwecn 4" and 44" c. The
Anodic chlorination of substituted benzenes - the choice of the chlorination reagents
โ Scribed by Jean Gourcy; Jacques Simonet; Michel Jaccaud
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 569 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract The work on the chlorination at ordinary temperatures of the lower olefines in the liquid phase, and in the presence of ferric chloride and antimony trichloride as catalysts, has been continued, and the reactions of propylene have been studied. As with ethylene, the main reaction was t
o f a paper read before the Institution o f Engineers-in-Charge, on February 9, l93t) iihdcrll ~ncthotls of water purificntion may incIucIc ((1) storage and ctcrntion, (Zt) addition of liuic or sochi t o correct acidity, (c) congulntioii to nssist sedimentation and to itnprorc (d) scclitncntntion, (
Abstraet~Polystyrene and poly-#,~-dideuterostyrene have been photo-chlorinated in solution in carbon tetrachloride. The products have been examined by i.r., 220 MI-lz NMR and laser Raman spectroscopy. For chlorination at 13ยฐ, approximately equal numbers of chlorine atoms are introduced at a-and ~-si
## THE CHLORINATION OF ETHYLENE DICHLORIDE Ug E. GALITZENSTEIN (the Ltc) and C. \VOOLF The chlorination of ethylene dichloridc to form mainly I : I : 2trichloroethanc has hecn investigated. Various catalysts have been tried, but with most of those described in the literature, e . ~. antimony chlo
## Abstract The title reaction, displaying peculiar characteristics as to relative rates and isomer distributions, has been studied in detail. Prior to this study, different mechanisms had been advanced by several groups. Kinetic features (isomer patterns, relative and absolute rates, reaction orde