𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The chlorination of ethylene and propylene. II. The chlorination of propylene

✍ Scribed by Galitzenstein, E. ;Woolf, C.

Publisher
Wiley (John Wiley & Sons)
Year
1950
Weight
340 KB
Volume
69
Category
Article
ISSN
0368-4075

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The work on the chlorination at ordinary temperatures of the lower olefines in the liquid phase, and in the presence of ferric chloride and antimony trichloride as catalysts, has been continued, and the reactions of propylene have been studied.

As with ethylene, the main reaction was that of addition at the double bond, but larger proportions of substituted by‐products were formed than with ethylene. Thus the chief product was 1 : 2‐dichloropropane (propylene dichloride). Of the five possible trichloropropanes, the 1:2: 3‐compound was predominant, but the 1:1:2‐ and 1:2: 2‐trichloropropanes were also present.

📜 SIMILAR VOLUMES

The chlorination of ethylene and propyle
The chlorination of ethylene and propylene. I. The chlorination of ethylene
✍ Galitzenstein, E. ;Woolf, C. 📂 Article 📅 1950 🏛 Wiley (John Wiley & Sons) ⚖ 435 KB

By E. CALITZENSTEIN (the laic) and C. \\'OOLF The chlorination of ethylene in the liquid phase to form I : 2dichloroethane (ethylene dichloride), has been investigated in some detail, catalysts such as antimony trichloride and ferric chloride being employed, at tempentures hctwecn 4" and 44" c. The

Permeation of chlorinated hydrocarbons t
Permeation of chlorinated hydrocarbons through nylon 6/ethylene–propylene rubber blends
✍ Soney C. George; K. N. Ninan; G. Geuskens; Sabu Thomas 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 277 KB

## Abstract Vapor transport offers one the unique ability to study structure–property relationships in polymers. An analysis of the transport of chlorinated hydrocarbons through nylon/ethylene–propylene rubber (EPR) blend membranes showed us how the permeation behavior varied according to the struc