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The chlorination of ethylene and propylene. I. The chlorination of ethylene

✍ Scribed by Galitzenstein, E. ;Woolf, C.

Publisher
Wiley (John Wiley & Sons)
Year
1950
Weight
435 KB
Volume
69
Category
Article
ISSN
0368-4075

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✦ Synopsis

By E. CALITZENSTEIN (the laic) and C. \'OOLF The chlorination of ethylene in the liquid phase to form I : 2dichloroethane (ethylene dichloride), has been investigated in some detail, catalysts such as antimony trichloride and ferric chloride being employed, at tempentures hctwecn 4" and 44" c. The effect of cxccss of either reactant has been studied, and the use of mixtures of ethylene with methane tried. The influence of sunlight and water in these rcacrions, and the formation of by-products such as I : I : 2-trichloroethanc and p-8'dichlorodicthyl ethcr, arc discussed.

'' Portnov and Scferovich, l'ruiis. Stare Iiisr. uppl. Cliciii.

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