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Anionic Polymerization of (Meth)acrylates in the Presence of Cesium Halide−Trialkylaluminum Complexes in Toluene

✍ Scribed by Schmitt, Bardo; Stauf, Wolfgang; Müller, H. E.

Book ID
126035015
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
110 KB
Volume
34
Category
Article
ISSN
0024-9297

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## Abstract The kinetics of the polymerization of methyl methacrylate initiated by lithium alkyls (__tert__‐butyllithium or ethyl α‐lithiobutyrate) was investigated in the presence of aluminium alkyls (triethylaluminium or triisobutylaluminium) in toluene at −78°C. The rate of polymerization decrea