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Anionic Polymerization of (Meth)acrylates in the Presence of Tetraalkylammonium Halide−Trialkyl Aluminum Complexes in Toluene, 1. Kinetic Investigations with Methyl Methacrylate

✍ Scribed by Schlaad, Helmut; Müller, Axel H. E.

Book ID
127370870
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
222 KB
Volume
31
Category
Article
ISSN
0024-9297

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Mechanism of anionic polymerization of (
Mechanism of anionic polymerization of (meth)acrylates in the presence of aluminium alkyls, 2. Kinetic investigations with methyl methacrylate in toluene
✍ Helmut Schlaad; Axel H. E. Müller 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 366 KB

## Abstract The kinetics of the polymerization of methyl methacrylate initiated by lithium alkyls (__tert__‐butyllithium or ethyl α‐lithiobutyrate) was investigated in the presence of aluminium alkyls (triethylaluminium or triisobutylaluminium) in toluene at −78°C. The rate of polymerization decrea