The constant progress of the anionic polymerization of (meth)acrylates is discussed from both the fundamental and practical points of view. A special attention is paid to the improved macromolecular engineering of (meth)acrylate-based (co)polymers. The resulting most important materials and the sca
Anionic polymerization of (meth)acrylic monomers: anionic polymerization oftert-butyl methacrylate in toluene
✍ Scribed by Zune, C; Dubois, P; Jérôme, R
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 99 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0959-8103
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✦ Synopsis
The anionic polymerization of tBMA initiated by an organolithium compound in toluene at low temperature (À78 °C and 0 °C) has been revisited. Under these experimental conditions, no `livingness' is reported, consistently with formation of an important fraction of oligomers (M n = 650).
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