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Anion-Templated Assembly of a [2]Catenane

✍ Scribed by Sambrook, Mark R.; Beer, Paul D.; Wisner, James A.; Paul, Rowena L.; Cowley, Andrew R.

Book ID
126262446
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
83 KB
Volume
126
Category
Article
ISSN
0002-7863

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The templating effect of the tetrafluoroborate ion leads to assembly of four Co ions and six bridging ligands around this anion to give a tetrahedral complex with a bridging ligand along each edge and the anion trapped in the central cavity (shown below). Surprisingly under identical conditions but