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Anion-Templated Assembly of a Supramolecular Cage Complex

✍ Scribed by James S. Fleming; Karen L. V. Mann; Charles-Antoine Carraz; Elefteria Psillakis; John C. Jeffery; Jon A. McCleverty; Michael D. Ward

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 115 KB
Volume: 37
Category: Article
ISSN: 0044-8249
DOI: 10.1002/(sici)1521-3773(19980518)37:9<1279::aid-anie1279>3.0.co;2-q

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✦ Synopsis

The templating effect of the tetrafluoroborate ion leads to assembly of four Co ions and six bridging ligands around this anion to give a tetrahedral complex with a bridging ligand along each edge and the anion trapped in the central cavity (shown below). Surprisingly under identical conditions but with Ni a simpler dinuclear complex forms.

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